N-(2,4,6-Trimethylphenyl)-1,3-thiazol-2-amine
نویسندگان
چکیده
In the title compound, C(12)H(14)N(2)S, the dihedral angle between the 1,3,5-trimethyl-benzene and 1,3-thia-zol-2-amine groups is 73.15 (4)°. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate R(2) (2)(8) loops.
منابع مشابه
N-(1,3-Thiazol-2-yl)-2-(2,4,6-trimethylphenyl)acetamide
In the title compound, C(14)H(16)N(2)OS, the thia-zole ring is essentially planar (r.m.s. deviation = 0.005 Å) and it forms a dihedral angle of 75.21 (8)° with the benzene ring. In the crystal, mol-ecules are linked into inversion dimers by pairs of N-H⋯N hydrogen bonds to generate R(2) (2)(8) loops.
متن کامل4-(2,4,6-Trimethylbenzyl)-1,3-thiazol-2-amine
The methyl-ene C atom in the title compound, C(13)H(16)N(2)S, is connected to a five-membered thia-zole ring and a mesityl substituent. The rings are aligned at 75.4 (1)°. The amino substitutent inter-acts with the ring N atom of an adjacent mol-ecule by an inter-molecular N-H⋯N hydrogen bond, generating a helical chain running along the b axis.
متن کامل(2,4,6-Trimethylphenyl){2-[N-(2,4,6-trimethylphenyl)formamido]ethyl}ammonium chloride
In the title salt, C21H29N2O(+)·Cl(-), the benzene rings form a dihedral angle of 6.13 (1)°. In the crystal, N-H⋯Cl hydrogen bonds link the cations and anions into chains extending along the c axis.
متن کامل4-Amino-N-(2,3-dihydro-1,3-thiazol-2-ylidene)benzenesulfonamide–2,4,6-tris(pyridin-2-yl)-1,3,5-triazine (1/1)
The sulfa-thia-zole mol-ecule in the title 1:1 co-crystal, C9H9N3O2S2·C18H12N6, adopts an approximate L-shape [dihedral angle between the five- and six-membered rings = 86.20 (9)°] and features an intra-molecular hypervalent S⋯O inter-action [2.8666 (15) Å]. Overall, the triazine mol-ecule has the shape of a disk as the pendant pyridine rings are relatively close to coplanar with the central ri...
متن کامل4-[(1,3-Thiazol-2-yl)sulfamoyl]phenyl 2,2,2-trifluoroacetate
In the title compound, C(11)H(7)F(3)N(2)O(4)S(2), the 1,3-thia-zol-2-amine residue is almost perpendicular to the central benzene ring [dihedral angle = 84.3 (2)°]. There is a small twist between the benzene ring and the ester group [C-O-C-C torsion angle = 9.8 (6)°]. Thus, the mol-ecule has an L-shape. Inversion-related dimers are connected in the crystal packing by pairs of N-H⋯N hydrogen bon...
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